I Introduction
An exciting period of exploration of the outer solar system is underway by spacecraft, by remarkably improved ground-based observations and by orbiting telescopes: International Ultraviolet Explorer (IUE) and Hubble Space Telescope (HST). These studies have revolutionized our understanding of the solar system revealing a kaleidoscope of unusual worlds. Because of the low surface temperatures, typically < 130K, ice is the 'rock' in the outer solar system. That is, excluding the four giant planets and Io, it is the structural and thermal properties of ice that determines the surface geology of many objects from the orbit of Jupiter outward (Burns and Matthews, 1986). Therefore, understanding the radiation chemistry of and desorption from ice or low-temperature hydrated minerals is critical. Other more volatile molecular species, such as N2, O2, CO, CO2, NH3, CH4, and SO2 form atmospheres and polar 'ices' or can cause the surface to be geologically active. Io, a moon of Jupiter, is an exception. Owing to its tidal interaction with Jupiter, Io is volcanically active and has lost its water and other light volatiles. Because of this, frozen SO2, a volcanic gas on earth, covers Io's surface (Burns and Matthews, 1986).
Since most small, outer solar system bodies, with the exception of Titan, have either no atmospheres or tenuous ones, their icy surfaces are exposed to the solar UV and to the local plasma causing desorption as well as physical and chemical alterations (Johnson, 1990; 1998). During the Voyager I tour of the outer solar system, W.L. Brown, L.J. Lanzerotti and colleagues at AT&T Bell Labs measured the ejection of molecules induced by energetic ion impact of ice. They discovered that the sputtering from low-temperature ices by fast, light ions is determined by the electronic excitations produced in the ice, rather than by knock-on collisions (Brown et al., 1978) and, hence, is an electronically-stimulated-desorption process. This exciting discovery opened a new field of study. Below the relevance of desorption to a few outer solar system bodies is described; for extended descriptions see Johnson (1990; 1996; 1998).
II Desorption from Solar System Bodies
The samples collected during the Apollo missions show the lunar surface is modified by the impacting solar-wind ions (~ 1 keV/u H+ and He++) and by energetic solar particles (Taylor, 1982). This aspect of planetary physics has recently been revived by the observation of Na and K 'atmospheres' around Mercury and the Moon (Potter and Morgan, 1985; 1988). Such atmospheres are produced by stimulated-desorption (the ions, electrons and UV photons) of these atoms from the rocky surfaces (Madey et al. 1998). The sodium atmosphere has been seen to extend to ~ 5 lunar radii from the moon's surface (Flynn and Mendillo, 1993), providing an impressive manifestation of desorption.
http://www.thunderbolts.info/forum/phpBB3/viewtopic.php?f=4&t=677&start=30
Sodium salts in E-ring ice grains from an ocean below
the surface of Enceladus
F. Postberg1,2, S. Kempf2,3, J. Schmidt4, N. Brilliantov5,6, A. Beinsen7, B. Abel7,8, U. Buck9 & R. Srama2
Saturn’s moon Enceladus emits plumes of water vapour and ice particles from fractures near its south pole1–5, suggesting the possibility of a
subsurface ocean5–7. These plume particles are the dominant source of Saturn’s E ring7,8. A previous in situ analysis9 of these particles
concluded that the minor organic or siliceous components, identified in many ice grains, could be evidence for interaction between Enceladus’ rocky
core and liquid water9,10. It was not clear, however, whether the liquid is still present today or whether it has frozen. Here we report the identification
of a population of E-ring grains that are rich in sodium salts ( 0.5–2% by mass), which can arise only if the plumes originate from liquid water.
The abundance of various salt components in these particles, as well as the inferred basic pH, exhibit a compelling similarity to the predicted
composition of a subsurface Enceladus ocean in contact with its rock core11. The plume vapour is expected to be free of atomic sodium. Thus, the
absence of sodium from optical spectra12 is in good agreement with our results. In the E ring the upper limit for spectroscopy12 is insufficiently
sensitive to detect the concentrations we found.
[url]zolotov.faculty.asu.edu/publ/Postberg-E-ring-salts-Nature.pdf[/url]
Growls from the Tiger Stripes: the Latest on Enceladus
Jennifer G. Winters
4. Tiger Stripes
As stated above, the ’tiger stripes’ were the first indication of interesting activity in
the south pole. These are four roughly parallel fractures, each about 130 km long and 300
m deep, flanked by ridges 100 m high. As the radius of Endeladus is only 250 km,
the fact that these features are so sizeable is remarkable. It is thought that these features
were formed by the upwelling of low density material (diapirism) as a result of tidal heating
(Nimmo & Pappalardo 2006). Figure 1 (from Porco et al. 2006) shows these fractures at
increasing magnifications in composites from Cassini’s NAC (Narrow Angle Camera). The
false blue-green color of B and C indicates the relatively coarse-grained ice particles that lie
within and just along the tiger stripes.
The temperature in the area of the tiger stripes is much higher than that of the surrounding
areas (114-157 K vs. 74-81 K) (Porco et al. 2006), due to a still unknown
geothermal source (see H 4.1 for further discussion), but it has been determined that the
high temperatures originate in or under the tiger stripes.
4.1. Geothermal Activity
Many have puzzled over the source of the abnormally high thermal activity occurring
at the tiger stripes. 4-8 GW of energy is being released from this area, known as the south
polar thermal anomaly. Radiogenic sources (those that release heat from radioactive decay
in an assumed differentiated chondritic rocky core) can only contribute 0.32 GW of this heat.
Other suggestions include shear heating from tidal forces (Nimmo & Pappalardo et al. 2007;
Hurford et al. 2007) and influences from the near-resonance with Dione (another of Saturn’s
moons) (Squyres et al. 1983). While these appear to be the most widely accepted causes
for the high energy being observed, Tobie et al. (2008) have proposed that friction due to
low viscosity in the boundary between the overlying ice layer and a possible subsurface sea
could generate enough energy to explain this thermal activity.
Abramov & Spencer (2009) observe that over the 16 month period between Cassini
flybys, the thermal emission varied by less than 15%, so it seems to be staying fairly constant
at this time. But Tobie et al.(2008) note that if there is liquid at depth, it is impossible to
sustain it over long timescales if the heat output is this great. Based on this, they propose
that the thermal emission rate at this time is abnormally high. And as if it is not difficult
enough to explain the extra heat, they have pointed out that this 4-8 GW of observed
energy does not include radiation that is outside the wavelength detection limits of the
CIRS (Composite Infrared Spectrometer) (7-1000 μm) or any heat flow from regions other
than the south polar area, so the total energy is probably even more than that observed.
This issue will remain a mystery until more conclusive data is received.
The location of this south pole anomaly (SPT) is also perplexing. Why are there tiger
stripes only at the south pole and not at both poles? Tobie et al. (2008) and Collins &
Goodman (2007) suggest that a negative gravity anomaly created by a subsurface sea, which
is created by the thermal output, will tend to reorient the satellite’s rotation axis so that the
hotspot is always at the south pole. This idea is a modification of one proposed by Nimmo
& Pappalardo (2006).
Figure 2 (from Tobie et al. 2008) shows a schematic of their model of the geothermal
processes occurring at the south pole, including a silicate core, a layer of liquid water, a
layer of warm ice, and then the overlying cold ice surface. Also illustrated are the vents and
plumes and the ’negative gravity anomaly’ due to the accumulation of melt.
http://www.chara.gsu.edu/~thenry/PLANETS/paper.winters.pdf


